Reactivity and fate of secondary alkane sulfonates (SAS) in marine sediments.

نویسندگان

  • Rosa María Baena-Nogueras
  • Patricia Rojas-Ojeda
  • José Luis Sanz
  • Eduardo González-Mazo
  • Pablo A Lara-Martín
چکیده

This research is focused on secondary alkane sulfonates (SAS), anionic surfactants widely used in household applications that access aquatic environments mainly via sewage discharges. We studied their sorption capacity and anaerobic degradation in marine sediments, providing the first data available on this topic. SAS partition coefficients increased towards those homologues having longer alkyl chains (from up to 141 L kg(-1) for C14 to up to 1753 L kg(-1) for C17), which were those less susceptible to undergo biodegradation. Overall, SAS removal percentages reached up to 98% after 166 days of incubation using anoxic sediments. The degradation pathway consisted on the formation of sulfocarboxylic acids after an initial fumarate attack of the alkyl chain and successive β-oxidations. This is the first study showing that SAS can be degraded in absence of oxygen, so this new information should be taken into account for future environmental risk assessments on these chemicals.

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عنوان ژورنال:
  • Environmental pollution

دوره 189  شماره 

صفحات  -

تاریخ انتشار 2014